破解锂电池热失控爆燃难题,奕普新材纳米级六角片状MC60获国家发明专利
电池中国获悉,近日,山东奕普新材料有限公司(简称“奕普新材”)自主研发的“六角片状氰尿酸三聚氰胺及其制备方法、应用”技术获得国家知识产权局发明专利授权。这一技术突破不仅填补了全球纳米级六角片状MCA的空白,更以独特的催化反应路径和纳米级粒径控制能力赋予该产品在国际上处于领先地位,为无卤阻燃材料领域带来革命性解决方案,标志着奕普新材在绿色化学与先进材料领域的全球竞争力迈上新台阶
01
开拓新市场:瞄准高端需求,抢占全球份额
据悉,传统MCA材料因粒径大、分散性差、晶型不稳定,耐温低等问题,主要应用于低端塑料阻燃领域。山东奕普新材通过突破性技术制备的纳米级六角片状氰尿酸三聚氰胺(MC60A),晶型为六角片状、平均粒径控制在0.3μm以下,且形貌均一、表面活性高,耐温高,特别适用于锂电池隔膜涂层,能有效解决锂电池热失控引发的爆燃问题。该产品广泛应用于超薄型挠性覆铜板(FCCL)、FFC绝缘膜、FFC补强板、电路板、光触媒、新能源汽车、航空航天复合材料等对阻燃性能要求严苛的高端领域。
02
技术突破:从“微米级”到“纳米级”的跃升
据介绍,传统MCA,晶型不稳定,平均粒径通常在2-10μm,且易团聚,导致阻燃效率低、加工性能差。奕普新材研发团队创新性地在MCA合成中引入催化剂,通过分步反应机制实现精准调,控制晶体沿六角片状方向生长,最终获得粒径分布窄(D50<0.3μm)、纳米级六角片状MCA粉末。该工艺突破了传统工艺的晶型和粒径瓶颈,阻燃效率提升40%,达到国际领先水平。
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理念革新:从“经验驱动”到“分子设计”的范式转换
山东奕普新材此次发明专利的核心突破,在于研发团队通过量子化学模拟,精准解析氢键作用机制,首次提出“模板诱导-定向生长”理论模型,实现了从分子尺度对产物形貌和性能的主动设计。这一理念革新打破了行业依赖“试错法”改进工艺的惯性思维,为开发下一代功能化高端MCA奠定了方法论基础。
对于山东奕普新材料而言,技术专利授权强化了奕普新材在纳米级六角片状氰尿酸三聚氰胺(MCA)领域的全球话语权,直接阻断竞争对手仿制路径;另外推动产业链升级,依托该技术,公司可向下游延伸开发定制化高利润产品,提升价值链掌控力;同时促进企业绿色转型加速,工艺过程零排放,契合欧盟REACH法规与“双碳”目标要求。
此次重大技术突破,山东奕普新材料不仅实现了下游无卤阻燃材料性能的跨越式提升,更探索出一条“基础研究-技术开发-产业转化”的高效路径。这一成果标志着中国企业在高端阻燃材料领域已从“跟跑”转向“领跑”,为全球无卤阻燃新材料产业升级贡献中国方案。
站在世界新技术制高点,奕普新材正以“创新者”的姿态,书写中国新材料产业的崛起故事。未来,山东奕普新材料将持续深耕无卤阻燃剂领域绿色制造技术,向着“全球高端材料领跑者”的目标阔步前行。
Solving the problem of thermal runaway and explosion in lithium batteries, Yipu New Material's nanoscale hexagonal sheet MC60 has been granted a national invention patent
Battery China learned that recently, the technology of "hexagonal flake cyanuric acid melamine and its preparation method and application" independently developed by Shandong Yipu New Material Co., Ltd. (hereinafter referred to as "Yipu New Material") was granted an invention patent by the China National Intellectual Property Administration. This technological breakthrough not only fills the gap in the global nanoscale hexagonal sheet MCA, but also gives the product a leading position internationally with its unique catalytic reaction pathway and nanoscale particle size control ability, bringing revolutionary solutions to the field of halogen-free flame retardant materials, marking a new level of global competitiveness for Yipu New Materials in green chemistry and advanced materials
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Exploring new markets: Targeting high-end demand and seizing global market share
It is reported that traditional MCA materials are mainly used in the field of low-end plastic flame retardancy due to their large particle size, poor dispersibility, unstable crystal structure, and low temperature resistance. Shandong Yipu New Materials has developed a breakthrough technology to prepare nanoscale hexagonal sheet cyanuric acid melamine (MC60A), which has a hexagonal sheet crystal structure, an average particle size controlled below 0.3 μ m, uniform morphology, high surface activity, and high temperature resistance. It is particularly suitable for lithium battery separator coatings and can effectively solve the problem of explosion caused by thermal runaway of lithium batteries. This product is widely used in high-end fields with strict requirements for flame retardancy, such as ultra-thin flexible copper-clad laminates (FCCL), FFC insulation films, FFC reinforcement boards, circuit boards, photocatalysts, new energy vehicles, aerospace composite materials, etc.
02
Technological breakthrough: leap from "micrometer level" to "nanometer level"
It is reported that traditional MCA has unstable crystal structure, with an average particle size usually between 2-10 μ m, and is prone to agglomeration, resulting in low flame retardant efficiency and poor processing performance. The research and development team of Yipu New Materials innovatively introduced catalysts in MCA synthesis, achieved precise tuning through a stepwise reaction mechanism, controlled crystal growth along the hexagonal sheet direction, and ultimately obtained narrow particle size distribution (D50<0.3 μ m), nanoscale hexagonal sheet MCA powder. This process breaks through the bottleneck of traditional processes in terms of crystal structure and particle size, and increases flame retardant efficiency by 40%, reaching the international leading level.
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Conceptual innovation: paradigm shift from "experience driven" to "molecular design"
The core breakthrough of Shandong Yipu New Materials' invention patent lies in the R&D team's precise analysis of hydrogen bonding mechanisms through quantum chemical simulations, and the first proposal of the "template induced directional growth" theoretical model, which enables active design of product morphology and properties at the molecular scale. This innovative concept breaks the industry's inertia of relying on the "trial and error method" to improve processes, laying a methodological foundation for the development of the next generation of functional high-end MCA.
For Shandong Yipu New Materials, the technology patent authorization has strengthened Yipu New Materials' global discourse power in the field of nanoscale hexagonal sheet cyanuric acid melamine (MCA), directly blocking competitors' imitation path; In addition, by promoting the upgrading of the industrial chain and relying on this technology, the company can extend the development of customized high profit products downstream, enhancing its control over the value chain; At the same time, it promotes the acceleration of enterprise green transformation, zero emissions in the process, and meets the requirements of the EU REACH regulation and the "dual carbon" target.
With this major technological breakthrough, Shandong Yipu New Materials not only achieved a leapfrog improvement in the performance of downstream halogen-free flame retardant materials, but also explored an efficient path of "basic research technology development industrial transformation". This achievement marks that Chinese enterprises have shifted from "following" to "leading" in the field of high-end flame retardant materials, contributing Chinese solutions to the upgrading of the global halogen-free flame retardant new material industry.
Standing at the forefront of new technologies in the world, Yipu New Materials is writing the rise story of China's new materials industry with the posture of an "innovator". In the future, Shandong Yipu New Materials will continue to deepen its green manufacturing technology in the field of halogen-free flame retardants, and stride towards the goal of becoming a "global leader in high-end materials".